| #Q001 | operational | operational | recommended | Process optimization for ozonation facilities | drinking water | For ozonation facilities, fluctuations in water quality may require treatment process adjustments to minimize bromate formation. As such, water utilities should be aware of how their process responds to water quality changes and adjust their treatment goals accordingly to optimize their process and minimize bromate formation. | Applies to facilities using ozonation | high |
| #Q002 | operational | operational | recommended | Best practices for hypochlorite solutions | drinking water | For facilities using hypochlorite solutions, bromate concentrations in drinking water can be minimized by applying the following best practices: 1. Use treatment chemicals that are certified as meeting NSF International (NSF)/American National Standards Institute (ANSI) Standard 60. 2. For water utilities using on-site systems for the generation of hypochlorite, use a low-bromide salt. 3. Follow the handling and storage recommendations outlined in Appendix B. 4. Establish a quality control program to verify product quality and manage solution storage. | Applies to facilities using hypochlorite solutions | high |
| #Q003 | monitoring | reporting | recommended | Bromate monitoring frequency | drinking water | At a minimum, quarterly monitoring of treated water from surface water and groundwater sources for bromate is recommended at facilities using ozone or hypochlorite solutions. | Facilities using ozone or hypochlorite solutions | high |
| #Q004 | monitoring | reporting | recommended | Bromate sampling location (treated water) | drinking water | Samples should be collected after treatment at the water treatment plant or well and before water is distributed. | | high |
| #Q005 | monitoring | reporting | recommended | Bromate sampling at rechlorination stations | drinking water | In systems with rechlorination stations using hypochlorite solutions, quarterly samples should also be collected where rechlorinated water enters the distribution system. | Systems with rechlorination stations using hypochlorite solutions | high |
| #Q006 | reporting | reporting | recommended | Compliance calculation method | drinking water | The guideline value should be compared with the locational running average of quarterly samples, as bromate levels can vary significantly over time, including seasonally, with factors such as the levels of organic matter in the raw water, temperature, and the handling and storage of hypochlorite solutions. | | high |
| #Q007 | operational | operational | recommended | Source water characterization for ozone facilities | drinking water | For facilities using ozone, water utilities should have a good understanding of the sources and concentration of bromide in their source waters and the seasonal variability of water quality parameters that may affect the formation of bromate (e.g., pH, alkalinity, organic matter, ammonia). | Facilities using ozone | high |
| #Q008 | monitoring | reporting | recommended | Bromide monitoring in raw water | drinking water | Quarterly monitoring of bromide in raw water is recommended in conjunction with treated water bromate monitoring, but this frequency may be reduced if drinking water monitoring for bromate does not show elevated levels. | Facilities using ozone | high |
| #Q009 | treatment | treatment | recommended | Universal disinfection recommendation | drinking water | In general, all drinking water supplies should be disinfected. | | high |
| #Q010 | treatment | treatment | recommended | Disinfectant residual maintenance | drinking water | Where applicable, an adequate concentration of disinfectant residual should be maintained throughout the distribution system at all times. | | high |
| #Q011 | monitoring | operational | recommended | Sample container requirements | drinking water | Samples should be collected in precleaned opaque plastic or amber glass bottles containing the appropriate quenching agent for the analytical method. | | high |
| #Q012 | monitoring | operational | recommended | Sample pretreatment | drinking water | Sample pretreatment methods should remove high concentrations of chloride, which may interfere with bromate measurement. | | high |
| #Q013 | administrative | reporting | mandatory | MDL Establishment Criteria | drinking water | MDLs must be established using specific quality control criteria. | | high |
| #Q014 | administrative | reporting | mandatory | MRL Quality Control Requirement | drinking water | MRLs can be used only if acceptable quality control criteria are met (U.S. EPA, 1997a, 1997b, 2001b, 2002, 2009a, 2009b). | | high |
| #Q015 | administrative | reporting | recommended | Laboratory coordination for MDLs/MRLs | drinking water | Water utilities should discuss sampling requirements with the accredited laboratory conducting the analysis to ensure that quality control procedures are met and that MDLs/MRLs are low enough to ensure accurate monitoring at concentrations close to the proposed MAC. | | high |
| #Q016 | administrative | reporting | recommended | Analytical method performance measures | drinking water | Water utilities should establish performance measures when specifying which analytical method to use (i.e., sample volume, sampling requirements, sample preservation and storage, MDL). | | high |
| #Q017 | treatment | treatment | mandatory | Disinfection effectiveness priority | drinking water | Process optimization to reduce the formation of DBPs, including bromate, must not compromise the effectiveness of disinfection. | | high |
| #Q018 | administrative | health | recommended | NSF/ANSI 60 certification for hypochlorite | drinking water | Water utilities should specify hypochlorite treatment chemicals that are certified as meeting NSF/ANSI Standard 60 in their purchasing documents (NSF/ANSI, 2014). | Utilities using hypochlorite solutions | high |
| #Q019 | administrative | health | mandatory | SPAC Compliance for Manufacturers | drinking water | Manufacturers of certified hypochlorite treatment chemicals are required to meet this SPAC to safeguard drinking water quality. | | high |
| #Q020 | administrative | operational | recommended | Quality control program for hypochlorite | drinking water | It is recommended that water utilities establish a quality control program to verify product quality and manage solution storage. | Utilities using hypochlorite solutions | high |
| #Q021 | monitoring | reporting | recommended | Bromide testing for rainwater/snowmelt sources | drinking water | Water sources that are highly dependent on rainwater or snowmelt should also be tested to determine the bromide concentration in raw water, particularly if drinking water is disinfected using ozonation or chlorination | Sources dependent on rainwater or snowmelt using ozonation or chlorination | high |
| #Q022 | operational | operational | recommended | Source water bromide characterization | drinking water | Water utilities should have a good understanding of the bromide concentrations in their source water to control the formation of bromate and other brominated DBPs. | | high |
| #Q023 | administrative | reporting | recommended | MRL evaluation for bromide analytical methods | drinking water | Water utilities should ensure that the MRL is low enough for their purposes when specifying which analytical method to use | | high |
| #Q024 | design | treatment | recommended | Ozone dosing location optimization | drinking water | The location where O3 will be dosed should be established as it relates to treatment objectives (i.e., pre-ozonation or intermediate ozonation). | Systems using ozone | high |
| #Q025 | operational | operational | recommended | Seasonal ozone dose optimization | drinking water | Water utilities should be aware of seasonal changes to optimize the applied O3 dose at all times while minimizing the formation of bromate and other DBPs. | Systems using ozone | high |
| #Q026 | monitoring | operational | recommended | Ozonation process monitoring | drinking water | Water quality, O3 consumption and energy consumption should be monitored to ensure that treatment objectives are met. | Systems using ozone | high |
| #Q027 | treatment | treatment | mandatory | No compromise to disinfection via DBP control | drinking water | It is critical that the effectiveness of disinfection not be compromised by any method used to control DBP concentrations in drinking water. | | high |
| #Q028 | operational | operational | recommended | Temperature effect awareness | drinking water | As water utilities cannot adjust the temperature during water treatment, they should be aware of seasonal changes and how their process responds for bromate and other DBP formation, so that they can adjust their water quality goals accordingly (Gillogly et al., 2001). | | high |
| #Q029 | operational | operational | recommended | NOM characterization | drinking water | Water utilities should have a good understanding of their water source and the nature and generation of NOM, whether it changes seasonally and how it relates to O3 demand and bromate formation. | | high |
| #Q030 | operational | treatment | mandatory | Ammonia addition consideration requirements | drinking water | As increased pH affects disinfection targets, water utilities must consider water quality characteristics when implementing ammonia addition as a control strategy. | When implementing ammonia addition | high |
| #Q031 | prohibition | treatment | recommended | Prohibition of H2O2 addition with disinfection | drinking water | If treatment objectives include both advanced oxidation and disinfection, H2O2 addition is not recommended (Hofmann, 2014). | When treatment objectives include both advanced oxidation and disinfection | high |
| #Q032 | operational | operational | recommended | Ozone system optimization strategies | drinking water | First, water utilities should have a good understanding of their source water characteristics (e.g., bromide, temperature, pH, alkalinity, NOM and ammonia), as well as how these change on a seasonal basis. Second, the O3 design dose should be determined relative to treatment objectives (e.g., disinfection, taste and odour control, colour removal, etc.) and seasonal source water characteristics. The location where O3 will be dosed (pre-ozonation or intermediate ozonation) should also be established as it relates to treatment objectives. | Municipal systems using ozone | high |
| #Q033 | operational | operational | mandatory | Control strategy trade-off consideration | drinking water | Water utilities must consider the trade-offs when implementing these control strategies, as outlined in Sections 7.3.4 and 7.3.7. | When implementing pH depression, ammonia, or chlorine-ammonia addition control strategies | high |
| #Q034 | design | treatment | recommended | Pre-ozonation pilot testing | drinking water | Bench- or pilot-scale testing is recommended prior to selecting ozonation to ensure it is the most appropriate solution with respect to water quality characteristics, treatment objectives and bromate formation. | Prior to selecting ozonation | high |
| #Q035 | treatment | treatment | recommended | Private supply disinfection recommendation | drinking water | All water supplies should be disinfected, including in cases where an individual household obtains its drinking water from a private supply. | Individual households with private supplies | high |
| #Q036 | operational | operational | recommended | Household hypochlorite handling precautions | drinking water | The precautions outlined in Section 7.2.2 should be followed when individual households use hypochlorite solutions as the source of chlorine to disinfect their water. | Individual households using hypochlorite solutions | high |
| #Q037 | monitoring | reporting | recommended | Bromide testing for private ozone systems | drinking water | Where ozone is used as the primary disinfectant, the water should be tested to determine bromide concentrations and other water quality characteristics. | Where ozone is used as primary disinfectant (residential/private) | high |
| #Q038 | treatment | treatment | recommended | Certification of residential treatment devices | drinking water | Health Canada does not recommend specific brands of drinking water treatment devices, but it strongly recommends that consumers use devices that have been certified by an accredited certification body as meeting the appropriate NSF/ANSI drinking water treatment unit standards. | When consumers use residential treatment devices | high |
| #Q039 | administrative | unknown | mandatory | Accreditation requirement for certification organizations | drinking water | Certification organizations provide assurance that a product conforms to applicable standards and must be accredited by the Standards Council of Canada (SCC). | | high |
| #Q040 | treatment | treatment | recommended | NSF/ANSI Standard compliance for residential devices | drinking water | it is recommended that drinking water treatment devices certified as meeting NSF/ANSI Standard 58 (Reverse Osmosis Drinking Water Treatment Systems), NSF/ANSI Standard 62 (Drinking Water Distillation Systems) or NSF/ANSI Standard 53 (Drinking Water Treatment Units - Health Effects) be used. | When consumers use residential treatment devices for bromate removal | high |
| #Q041 | design | operational | recommended | Point-of-use installation for RO and distillation | drinking water | Water that has been treated using RO or distillation may be corrosive to internal plumbing components. Therefore, these devices should be installed only at the point of use. In addition, these two types of drinking water treatment systems are intended only for point-of-use installation, as large quantities of influent water are needed to obtain the required volume of treated water, and are generally not practical for point-of-entry installation at the residential scale. | When installing RO or distillation devices | high |
| #Q042 | monitoring | operational | recommended | Verification testing of residential treatment devices | drinking water | Periodic testing by an accredited laboratory should be conducted on both the water entering the treatment device and the finished water to verify that the treatment device is effective. | For consumers using residential treatment devices | high |
| #Q043 | operational | operational | recommended | Maintenance of residential treatment devices | drinking water | Consumers should verify the expected longevity of the components in their treatment device according to the manufacturer's recommendations and service it when required. | For consumers using residential treatment devices | high |
| #Q044 | operational | operational | recommended | Dilution of hypochlorite solutions | drinking water | 1. Dilute stored hypochlorite solutions upon delivery | Handling and storage of hypochlorite solutions | high |
| #Q045 | operational | operational | recommended | Temperature control for hypochlorite storage | drinking water | 2. Store the hypochlorite solutions at lower temperatures: ... To minimize temperature increases, the product should be stored out of direct sunlight. | Handling and storage of hypochlorite solutions | high |
| #Q046 | operational | operational | recommended | pH control for hypochlorite storage | drinking water | 3. Control the pH of stored hypochlorite solutions at pH 11−13. even after dilution: Storage of concentrated hypochlorite solutions at pH values lower than 11 is not recommended ... utilities should continue to insist that manufacturer specifications include pH control in the range of 11−13. | Handling and storage of hypochlorite solutions | high |
| #Q047 | operational | operational | recommended | Use timeline for OSG hypochlorite | drinking water | Given the typical pH range of On-Site Generation (OSG) hypochlorite (pH 9 − 10), such solutions should be used as soon as possible after manufacture and should not be stored for more than 1−2 days. | When using OSG hypochlorite | high |
| #Q048 | operational | operational | recommended | Removal of transition metal ions | drinking water | 4. Control the removal of transition metal ions by purchasing filtered hypochlorite solutions and by using low-metal ion concentration feed water for the OSG systems and dilution water | Handling and storage of hypochlorite solutions | high |
| #Q049 | operational | operational | recommended | Use of fresh hypochlorite solutions | drinking water | 5. Use fresh hypochlorite solutions when possible: ... Rotate stock and minimize the quantity of aged product in storage tanks prior to the delivery of new product. | Handling and storage of hypochlorite solutions | high |
| #Q050 | operational | operational | recommended | Low-bromide salt for OSG hypochlorite | drinking water | 6. For utilities using OSG hypochlorite, use a low-bromide salt to minimize the amount of bromide present in the brine | Utilities using OSG hypochlorite | high |
| #Q051 | administrative | reporting | recommended | Implementation guidance source | drinking water | Specific guidance related to the implementation of drinking water guidelines should be obtained from the appropriate drinking water authority in the affected jurisdiction. | | high |
| #Q052 | monitoring | operational | guidance | Sample transportation and storage temperature | drinking water | Temperature specifications may apply during transportation and storage of samples. | | high |
| #Q053 | operational | operational | recommended | Ozone system optimization goal | drinking water | The goal for optimized system operation should be to meet treatment objectives with the lowest possible O3 dose (Rakness et al., 1996). | Systems using ozone | high |
| #Q054 | operational | operational | recommended | Hypochlorite verification program | drinking water | AWWA Standard B300 also recommends a verification program to confirm that hypochlorite treatment chemicals meet specifications (ANSI/AWWA, 2010). | Facilities using hypochlorite solutions | high |
| #Q055 | administrative | reporting | recommended | Bromide MDL recommendation | drinking water | A minimum MDL of 0.01 mg/L (10 µg/L) is recommended for bromide (Westerhoff, 2014). | | high |
| #Q056 | treatment | treatment | guidance | Biologically active filtration necessity | drinking water | As a result, biologically active filtration may be necessary. | Where ozone use increases biologically available organic content | high |